Main studies carried out during May:


- TEM ad SEM investigations of ribbons microstructure in as spun state and after annealing
- Chemical composition analysis combined with elemental mapping of sample after in-situ heating and after isothermal annealing to investigate changes in elements distribution within quasicrystalline particles after thermal treatment
- determination of the sequence of crystalline phase formation based on data obtained from transmission electron microscopy and XRD analysis
- analysis of the results obtained so far,
- participation in the local composite platform meeting
- participation in seminars and lectures
- receiving the scholarship from the Doctus program

In May due to upcoming EMAS workshops, effort was done to prepare more zinc samples in order to confirm previous observations and collect proper amount of data for statistics. Unfortunately as previous EBSD observations revealed, preparation of zinc samples in a way that no distortion to the crystalline lattice and no twins are introduced is considerable problem and cannot be carried out in short time span. This is true especially for preparation of samples from non deformed zinc (initial state) which is generally softer and quite easily deformed during cutting and grinding. Introduced layer of deformation with deformation twins is then extremely hard to remove during mechanical polishing as affected layer can have thickness up to hundreds of micrometers (at least one grain layer). Partial solution to this problem is removal of deformed and twinned material during chemical etching. This method is faster and does not introduce additional deformation, however it also does not produce flat, even surface. This is due to differences of etching speed of crystals in different orientations, as well as much faster etching of grain boundaries. Because of this etching has to be followed with careful grinding on 2500 SiC grinding paper in order to remove topography and produce surface suitable for EBSD analysis.

May was a month when I totally rearranged the vision of my program and made some steps towards analysis of experimental data.
Thousands of lines of code were developed making my program a tool for users not only for the author.

In may I continued spectrophotometric and voltamperometric studies of citrate bath with various concentrqtions of zinc sulpate ant sodium molybdate. I also lead the electrodeposition procesess in potentiostatic and coulostatic conditions on the steel and copper surfaces, from stable homogeneous and Zn(II)-Mo(VI) citrate baths, in the slightly acid range (pH about 5), with different concentration of metals and citrate ions.

From 14th to 25th May I participate in course “Electrocemical Impedance Spectroscopy and its applications” at Faculty of Chemistry of University of Warsaw.
Outline
1. AC response of Electrical Circuits, Laplace and Fourier transform
2. Impedance of Electrical Circuits and impedance graphs
3. Impedance measurements
4. Impedance of faradaic reactions in the presence of diffusion
5. Impedance of a faradaic reaction involving adsorption of reacting species
6. Dispersion of impedances on solid electrodes
7. Impedance of porous electrodes
8. Conditions for "good" impedances, stability, Kramers-Kronig Transforms
9. Modeling of experimental data
10. Selected applications
11. Exercises using computers

Course was given by prof. A. Lasia from Sherbrooke University (Canada).

This month I was wocused on investigations of the Crofer 22APU samples recieved from Foundry Research Institute. I was using EDS and WDS to measure chemical composition of surface oxide layers formed upon annealing in oxidative envitoment.